PHOTOCHEMICAL FRIES REARRANGEMENT OF N-PHENYL-2-PYRROLIDONE

被引：4

作者：

OHTA, S

SANO, A

YAMASHITA, M

OKAMOTO, M

机构：

[1] Kyoto Parmaceutical University, Yamashinaku, Kyoto, 607

来源：

HETEROCYCLES | 1993年 / 36卷 / 04期

关键词：

D O I：

10.3987/COM-92-6217

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photochemical Fries rearrangement of 1-phenyl-2-pyrrolidone (1) proceeded smoothly in methanol especially in the presence of piperylene. Continuous photo-irradiation of 1 successfully was carried out to raise the yield by utilizing a reaction mixture-circulation system consisting of a spiral quartz cell, a pump, a uv light source and a column packed with appropriate absorbents for the Fries rearranged product (3) and pigments.

引用

页码：743 / 749

页数：7

共 9 条

[1] PHOTOANILIDE REARRANGEMENT [J].