INFLUENCE OF PHYSICAL CHARACTERISTICS OF CHROMIA-ALUMINA ON ITS CATALYTIC ACTIVITY

被引：13

作者：

KURIACOSE, JC

DANIEL, C

机构：

[1] Department of Chemistry, Indian Institute of Technology, Madras

来源：

JOURNAL OF CATALYSIS | 1969年 / 14卷 / 01期

关键词：

D O I：

10.1016/0021-9517(69)90358-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dehydration and dehydrogenation of isopropanol has been studied on sintered, powdered, and pelleted chromia-alumina catalysts. With the powdered and pelleted catalysts the extent of dehydrogenation passes through a maximum as the temperature is raised from 380 °C keeping the contact time constant, while with the sintered catalyst there is a normal increase in extent of dehydrogenation with increase in temperature. The type of semiconductivity and the pore distribution of these catalysts have been investigated. The observed results for the dehydrogenation are discussed and explained on the basis of the semiconductor characteristics and texture of the catalysts. © 1969.

引用

页码：77 / +

页数：1

共 16 条

[1] THE SURFACE AREA AND CATALYTIC ACTIVITY OF ALUMINUM OXIDE [J].

BREY, WS ;

KRIEGER, KA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (11) :3637-3641

[2] THE PHYSICAL PROPERTIES OF CHROMIUM OXIDE ALUMINIUM OXIDE CATALYSTS .2. ELECTRICAL PROPERTIES [J].

CHAPMAN, PR ;

GRIFFITH, RH ;

MARSH, JDF .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1954, 224 (1158) :419-426

[3]

DELABANDA JFG, 1960, AF615141330 CONTR

[4]

EMMETT PH, 1960, CATALYSIS ED, V7, P142

[5]

JELLINEK MH, 1948, ADV CATAL, V1, P272

[6]

KURIACOSE JC, TO BE PUBLISHED

[7]

KURIACOSE JC, 1965, 3 P INT C CATALYSIS, P507

[8]

KURIACOSE JC, 1967, CURR SCI INDIA, V36, P606

[9] CORRELATION OF SURFACE AREA AND DEHYDROGENATION ACTIVITY FOR A CHROMIA ALUMINA CATALYST [J].

OWEN, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (10) :2559-2560

[10]

PANDAO SN, 1963, INDIAN J TECHNOL, V1, P102

← 1 2 →