KINETICS OF CAO-QUARTZ-H2O REACTION AT 120-DEGREES-C TO 180-DEGREES-C IN SUSPENSIONS

被引:32
作者
CHAN, CF
SAKIYAMA, M
MITSUDA, T
机构
[1] Materials Research Laboratory, Nagoya Institute of Technology, Showa-ku, Nagoya, Gokiso
关键词
D O I
10.1016/0008-8846(78)90052-2
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Kinetics of hydrothermal reactions have been studied for mixtures of CaO and quartz (<10 μm 10-20 μm) with Ca/Si = 0.8 and 1.0 in stirred suspensions at 120 - 180°C. Reaction proceeds through the sequence: Ca(OH)2 + SiO2 → Ca-rich C-S-H + SiO2 (at 120°C) → poorly crystalline tobermorite (at 140°C)→ highly crystalline tobermorite (at 180°C) → xonotlite at 180°C and Ca/Si = 1.0 and 180°C and Ca/Si = 0.8 if 10-20 μm quartz is used. Reaction is controlled by dissolution of the quartz. For both Ca/Si ratios the radius of the 10-20 μm quartz decreases at a constant rate, viz 0.85 μm/h at 180°C, 0.13 μm/h at 140°C, 0.04 μm/h at 120°C. © 1977.
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页码:1 / 6
页数:6
相关论文
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