UNSATURATED SULPHINAMIDES .7. UNUSUAL LITHIATION OF 4-(1',2'-ALKADIENESULPHINYL)-MORPHOLINES - PREPARATION OF SUBSTITUTED PROPARGYLIC SULPHINAMIDES AND THEIR HYDROLYTIC DESULPHINYLATION INTO THE CORRESPONDING ALLENES

被引：12

作者：

BAUDIN, JB

JULIA, SA

RUEL, O

WANG, Y

机构：

[1] Laboratoire de Chimie associé au C.N.R.S., Ecole Normale Supérieure, 75231 Paris Cedex 05

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)94373-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By deprotonation with methyllithium and reaction with water, deuterium oxide or alkyl halide, the γ-monosubstituted allenic sulphinamides 3 have been converted into the substituted propargylic sulphinamides 4 which were hydrolysed or deuterolysed with loss of sulphur dioxide to provide the corresponding allenes 5. © 1990.

引用

页码：213 / 216

页数：4

共 6 条

[1] COMPLEX-INDUCED PROXIMITY EFFECTS - REMOTE LITHIATIONS OF CARBOXAMIDES [J].