METAL-ION-CATALYZED FLUXIONALITY OF PENTADIENYLTINS AND ITS APPLICATION TO THE DIELS-ALDER REACTION

被引：16

作者：

NISHIGAICHI, Y

TAKUWA, A

IIHAMA, K

YOSHIDA, N

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 04期

关键词：

D O I：

10.1246/cl.1991.693

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Z)-Pentadienyltins (PDT) as well as (Z)-allylic tins are isomerized to (E)-isomers most effectively by alkaline earth metal ions. The resulted (E)-PDT is trapped by 1,4-naphthoquinone to give the Diels-Alder adducts efficiently behaving as a reactive equivalent of 1,3-pentadiene.

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页码：693 / 696

页数：4

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