ROTATIONALLY RESOLVED OVERTONE TRANSITIONS OF (GEH4)-GE-70 IN THE VISIBLE AND NEAR-INFRARED

被引:33
作者
CAMPARGUE, A
VETTERHOFFER, J
CHENEVIER, M
机构
[1] Laboratoire de Spectrométrie Physique1 1 Associated with CNRS (URA 008)., Université Joseph Fourier de Grenoble, 38402 Saint-Martin-d'Heres Cedex
关键词
D O I
10.1016/0009-2614(92)85481-O
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The DELTA-nu(GeH) = 6, 7 and 8 overtone transitions of natural germane and of mono isotopic germane (GeH4)-Ge-70 have been measured with rotational resolution by intracavity laser absorption spectroscopy. The DELTA-nu(GeH) = 6 and 7 rotational structure is found to be that of a pseudo-symmetric top as expected for this molecule close to the local mode limit. On the other hand the DELTA-nu(GeH) = 8 shows a more complicated structure which has not yet been analyzed.
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页码:353 / 356
页数:4
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