DIASTEREOSELECTIVE ADDITION OF METAL-COORDINATED AND NAKED TRI-SEC-BUTYLBOROHYDRIDES TO A NOREPHEDRINE-DERIVED 2-ACETYLOXAZOLIDINE

被引:26
作者
MANZONI, L
PILATI, T
POLI, G
SCOLASTICO, C
机构
[1] UNIV MILANO,CTR CNR STUDIO SOSTANZE ORGAN NAT,DIPARTIMENTO CHIM ORGAN & IND,VIA VENEZIAN 21,I-20133 MILAN,ITALY
[2] CTR STUDIO RELAZ TRA STRUTT & REATTIV CHIM,I-20124 MILAN,ITALY
关键词
D O I
10.1039/c39920001027
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The addition of tri-sec-butylborohydrides to the 2-acetyl-1,3-oxazolidine 1 can be directed with high selectivity to either the Si or the Re pi-carbonyl face under chelating or non-coordinating conditions, respectively.
引用
收藏
页码:1027 / 1029
页数:3
相关论文
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