OXIDATION OF INDOLES BY SINGLET OXYGEN AND DIMETHYLDIOXIRANE - ISOLATION OF INDOLE DIOXETANES AND EPOXIDES BY STABILIZATION THROUGH NITROGEN ACYLATION

被引：35

作者：

ADAM, W

AHRWEILER, M

SAUTER, M

SCHMIEDESKAMP, B

机构：

[1] Institut für Organische Chemie, Universität Würzburg, D-8700 Würzburg, Am Hubland

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 33期

关键词：

INDOLES; CARBAZOLES; DIMETHYLDIOXIRANE; SINGLET OXYGEN; DIOXETANES; EPOXIDES;

D O I：

10.1016/S0040-4039(00)73964-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stabilization through N-acylation allowed the isolation of the labile indole dioxetanes 2, which were transformed by dimethyl sulfide deoxygenation to the corresponding indole epoxides 5; the latter were also independently prepared by dimethyldioxirane oxidation.

引用

页码：5247 / 5250

页数：4

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