A STUDY OF CHLORINATED POLYACETYLENE

被引：12

作者：

CATALDO, F

机构：

[1] PROGEGA s.n.c., 00128 Rome

来源：

EUROPEAN POLYMER JOURNAL | 1993年 / 29卷 / 12期

关键词：

Polyacetylenes;

D O I：

10.1016/0014-3057(93)90258-H

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyacetylene obtained using Rh(I) complexes was chlorinated both as a film in a gas/solid system and as a suspension in chlorinated solvents. The structures of the products were studied by i.r. and electronic spectroscopy. The presence of unreacted polyene segments and a high degree of stereoregularity in the chlorinated portion was detected. The thermal stability of chlorinated polyacetylene and its chlorine content were investigated by thermogravimetry and differential thermal analysis. The maximum decomposition rate was recorded at 170-degrees.

引用

页码：1635 / 1639

页数：5

共 10 条

[1] STEREOSPECIFIC CHLORINATION OF POLYACETYLENE BY CHEMICAL DOPING [J].