ASYMMETRIC CATALYSIS .86. ENANTIOSELECTIVE EPOXIDATION OF N-ALLYLTRICHLOROACETAMIDE WITH TERT-BUTYLHYDROPEROXIDE AND MO-DOTED Y-ZEOLITES, SILICA-GEL, AS WELL AS ISOPROPYL TARTRATE

被引：8

作者：

BRUNNER, H

STUMPF, A

机构：

来源：

MONATSHEFTE FUR CHEMIE | 1994年 / 125卷 / 05期

关键词：

EPOXIDATION; ENANTIOSELECTIVITY; N-ALLYLTRICHLOROACETAMIDE DERIVATIVES; ISOPROPYL TARTRATE; MO-DOTED Y-ZEOLITES;

D O I：

10.1007/BF00811839

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-Allyl-trichloroacetamide was epoxidized with tert-butylhydroperoxide in toluene to give N-2,3-(epoxypropyl)trichloroacetamide with an enantiomeric excess of up to 43% ee. The enantioselective heterogeneous catalysts used were Mo-doted Y-zeolites and silicagel modified with 2R,3R-(+)-isopropyl tartrate.

引用

页码：485 / 489

页数：5

共 10 条

[1] ASYMMETRICAL CATALYSTS .64. ENANTIOSELECTIVE EPOXIDATION OF N-ALKYL-TRICHLOROACETAMIDE WITH OPTICALLY-ACTIVE MO CATALYSTS [J].