POLAROGRAPHIC REDUCTION OF 6-CHLOROQUINOLINE IN DIMETHYLFORMAMIDE

被引:5
作者
FUJINAGA, T
TAKAOKA, K
机构
[1] Chemical Institute, Faculty of Science, Kyoto University, Kyoto
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1968年 / 16卷 / 01期
关键词
D O I
10.1016/0368-1874(68)87041-8
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The polarographic behavior of 6-chloroquinoline in DMF solutions containing 0-90% water, and the effects of phenol and perchloric acid indicate the following mechanism for the reduction of 6-chloroquinoline at the dropping mercury electrode (the reactions are arranged in order of half-wave potentials). In the presence of less than 20% water: {A figure is presented}. In the presence of more than 20% of water: {A figure is presented} where R, RH2, QH and QH3 denote 6-chloroquinoline, 6-chlorodihydroquinoline, quinoline and dihydroquinoline, respectively. © 1968.
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页码:99 / &
相关论文
共 5 条
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FUJINAGA, T ;
IZUTSU, K ;
TAKAOKA, K .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1966, 12 (03) :203-&
[2]  
FUJINAGA T, 1964, J CHEM SOC JAPAN PUR, V85, P811
[3]  
FUJINAGA T, 1968, J ELECTROANAL CHEM, V16, P98
[4]  
MATSUO T, 1953, J CHEM SOC JAPAN IND, V56, P70
[5]  
TAKAOKA K, 1966, PEVIEW POLAROGRAPHY, V14, P63