TEMPLATE-CONTROLLED OLIGOMERIZATION SUPPORT STUDIES - TEMPLATE SYNTHESIS AND FUNCTIONALIZATION

被引：26

作者：

FELDMAN, KS

BOBO, JS

ENSEL, SM

LEE, YB

WEINREB, PH

机构：

[1] Department of Chemistry, The Pennsylvania State University, University Park

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 02期

关键词：

D O I：

10.1021/jo00289a019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trams-anti-trans-norbornadiene trimer 5. Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers. Lactonization studies with template diol 10 provide a useful measure of the “effective molecular size” of the template. © 1990, American Chemical Society. All rights reserved.

引用

页码：474 / 481

页数：8

共 59 条

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