POTENTIAL-INDUCED VARIATIONS IN PROPERTIES FOR CO ADSORBED ON A PLATINUM-ELECTRODE

被引：95

作者：

MEHANDRU, SP ^{[1
]}

ANDERSON, AB ^{[1
]}

机构：

[1] CASE WESTERN RESERVE UNIV,DEPT CHEM,CLEVELAND,OH 44106

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1989年 / 93卷 / 05期

关键词：

Electrodes--Platinum; -; Molecules--Adsorption; Spectroscopy; Infrared;

D O I：

10.1021/j100342a066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A brief summary of the various theoretical models to explain the potential-induced vibrational frequency shifts of molecules adsorbed on electrode surfaces is presented. Possible implications of studies involving emersed electrodes for enhancing this understanding are discussed. The results of the variations of CO properties as a function of potential on a platinum electrode are given, based on the atom superposition and electron delocalization molecular orbital theory, the valence band shift model, and a large cluster model of Pt(111).

引用

页码：2044 / 2047

页数：4

共 56 条

[1] DERIVATION OF EXTENDED HUCKEL METHOD WITH CORRECTIONS - ONE ELECTRON MOLECULAR-ORBITAL THEORY FOR ENERGY-LEVEL AND STRUCTURE DETERMINATIONS
ANDERSON, AB
[J]. JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (03) : 1187 - 1188
[2] STRUCTURES AND REACTIONS OF H3O+, H2O, AND OH ON AN FE ELECTRODE - POTENTIAL DEPENDENCE
ANDERSON, AB
RAY, NK
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (04) : 488 - 494
[3] DERIVATION OF AND COMMENTS ON BONACCORSI-SCROCCO-TOMASI POTENTIALS FOR ELECTROPHILIC ADDITIONS
ANDERSON, AB
[J]. JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (06) : 2477 - 2479
[4] THEORY FOR C-N- AND AG-C VIBRATIONAL FREQUENCY-DEPENDENCE ON POTENTIAL - CYANIDE ON A SILVER ELECTRODE
ANDERSON, AB
KOTZ, R
YEAGER, E
[J]. CHEMICAL PHYSICS LETTERS, 1981, 82 (01) : 130 - 134
[5] FACTORS DETERMINING CO ADSORPTION SITES ON PD AND PT(100) AND PT(111) SURFACES - THEORETICAL-STUDY
ANDERSON, AB
AWAD, MK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 7854 - 7857
[6] FIELD-INDUCED VIBRATIONAL FREQUENCY-SHIFTS OF CO AND CN CHEMISORBED ON CU(100)
BAGUS, PS
NELIN, CJ
MULLER, W
PHILPOTT, MR
SEKI, H
[J]. PHYSICAL REVIEW LETTERS, 1987, 58 (06) : 559 - 562
[7] INFRARED STUDY OF ADSORBED SPECIES ON ELECTRODES - ADSORPTION OF CARBON-MONOXIDE ON PT, RH AND AU
BEDEN, B
BEWICK, A
KUNIMATSU, K
LAMY, C
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 142 (1-2): : 345 - 356
[8] A STUDY BY ELECTROCHEMICALLY MODULATED INFRARED REFLECTANCE SPECTROSCOPY OF THE ELECTROSORPTION OF FORMIC-ACID AT A PLATINUM-ELECTRODE
BEDEN, B
BEWICK, A
LAMY, C
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 148 (01): : 147 - 160
[9] BEDEN B, 1981, J ELECTRONAL CHEM, V121, P243
[10] INSITU INFRARED-SPECTROSCOPY OF THE ELECTRODE ELECTROLYTE SOLUTION INTERPHASE
BEWICK, A
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 150 (1-2): : 481 - 493

← 1 2 3 4 5 6 →