2-DIMENSIONAL ROTATIONAL DYNAMIC CHIRALITY AND A CHIRALITY SCALE

被引:34
作者
HELOR, Y
PELEG, S
AVNIR, D
机构
[1] HEBREW UNIV JERUSALEM,DEPT COMP SCI,IL-91904 JERUSALEM,ISRAEL
[2] HEBREW UNIV JERUSALEM,F HABER RES CTR MOLEC DYNAM,DEPT ORGAN CHEM,IL-91904 JERUSALEM,ISRAEL
关键词
D O I
10.1021/la00101a012
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A scale for the quantitative assessment of the degree of shape chirality and for the absolute assignment of handedness is developed. The scale is based on a new definition of chirality, which, in turn, is based on the dynamic rotational properties of molecules. These concepts and their demonstration are carried out for the case of two-dimensional chirality, i.e., for chirality issues associated with adsorbate-surface interaction. © 1990, American Chemical Society. All rights reserved.
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页码:1691 / 1695
页数:5
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