POLYKETONES VIA OXIDATION OF POLYBUTADIENES CATALYZED BY COMPLEXES OF PLATINUM(II)

被引：27

作者：

IRAQI, A ^{[1
]}

COLEHAMILTON, DJ ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 09期

关键词：

D O I：

10.1016/S0277-5387(00)86919-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polybutadienes containing different ratios of 1,4- and 1,2-polymerized units are converted to polyketones by oxidation with (t)BuOOH in the presence of catalytic quantities of [Pt(diphoe)CF3(CH2Cl2)]+ (diphoe = Ph2PCH=CHPPh2); reactivity ratios for the different double bonds are determined as pendant/trans/cis, 6:5:3.

引用

页码：993 / 995

页数：3

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