PEROXYCHROMIUM COMPOUNDS

被引：6

作者：

ARMSTRONG, R

GIBSON, NA

机构：

[1] School of Chemistry, University of Sydney, NSW

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1968年 / 21卷 / 04期

关键词：

D O I：

10.1071/CH9680897

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formulae and properties of certain blue and violet peroxyohromium compounds have been investigated, and structures suggested. The blue adducts can be represented as organic base, Cr(O2)2O, blue anions as Cr(O2)2OX-where X is Cl or Br, and the violet anions as Cr(O2)2O2H−, where His thought to be hydrogen-bonded between two oxygen atoms. A relationship between these different forms is suggested. The various properties investigated for the peroxychromium compounds include magnetic susceptibilities, number of peroxy groups, conductivities, molecular weight measurements, and visible, infrared, and N.M.R. spectra. © 1968 CSIRO. All rights reserved.

引用

页码：897 / +

页数：1

共 14 条

[1] ARMSTRONG R, 1964, THESIS U SYDNEY
[2] THE CHROMIC ACID OXIDATION OF ISOPROPYL ALCOHOL IN 86.5-PERCENT ACETIC ACID SOLUTION - THE CHEMISTRY OF THE CHLOROCHROMATE ION
COHEN, M
WESTHEIMER, FH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (17) : 4387 - 4391
[3] CONNOR JA, 1964, ADV INORG CHEM, V6, P279
[4] COTTON FA, 1966, ADV INORG CHEM, P828
[5] DWYER FP, 1953, CHEM IND-LONDON, P153
[6] BLUE PERCHROMIC ACID
EVANS, DF
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1957, (SEP): : 4013 - 4018
[7] TITRATIONS WITH EXTRACTIVE END-POINTS .2. THE DICHROMATE TITRATION
GIBSON, NA
WHITE, RA
[J]. ANALYTICA CHIMICA ACTA, 1955, 12 (05) : 413 - 417
[8] THE FORMATION AND CONSTITUTION OF THE PERCHROMATES
GLASNER, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1950, (OCT): : 2795 - 2798
[9] TRANSITION-METAL PEROXY-COMPLEXES .1. VIOLET PERCHROMATES
GRIFFITH, WP
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (10): : 3948 - &
[10] STUDIES ON TRANSITION-METAL PEROXY-COMPLEXES .3. PEROXY-COMPLEXES OF GROUPS 4A VA + 6A
GRIFFITH, WP
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (DEC): : 5248 - &

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