CRYSTAL SPECTRA OF HEXAUREA COMPLEXES .3. OPTICAL AND MAGNETIC PROPERTIES OF CRYSTALS CONTAINING HEXAUREA VANADIUM (3) ION

被引：26

作者：

DINGLE, R

MCCARTHY, PJ

BALLHAUS.CJ

机构：

[1] Bell Telephone Laboratories, Incorporated, Murray Hill

[2] Department for Physical Chemistry, B. C. ØRsted Institute, University of Copenhagen, Copenhagen

[3] Canisius College, Buffalo, NY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 05期

关键词：

D O I：

10.1063/1.1671314

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Low-temperature polarized crystal spectra of the [V(urea)6] 8+ ion are presented and discussed. In many ways they closely resemble those seen in V3+/Al2O3. The ground-state splitting of 3A2 has been established by both optical and magnetic means and is reported as 6.0±0.5 cm-1. The source of spectral intensity is almost entirely due to the influence of the static, odd crystal field.

引用

页码：1957 / &

共 14 条

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