NITROGEN 1S ELECTRON BINDING ENERGIES . CORRELATIONS WITH MOLECULAR ORBITAL CALCULATED NITROGEN CHARGES

被引：285

作者：

HENDRICKSON, DN

HOLLANDER, JM

JOLLY, WL

机构：

[1] Department of Chemistry, University of California, Inorganic Materials Research Division, Lawrence Radiation Laboratory, Berkeley, Calif.

[2] Nuclear Chemistry Division, Lawrence Radiation Laboratory, Berkeley, Calif.

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 12期

关键词：

D O I：

10.1021/ic50082a020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nitrogen Is electron binding energies are given for 56 nitrogen compounds. Correlations are observed between these measured binding energies and nitrogen atom charges calculated from either CNDO or extended Hiickel molecular orbitals. The molecular structure of the oxyhyponitrite ion (N2O32-) and the bonding characteristics of various metal-coordinated ligands are investigated by means of these correlations. © 1969, American Chemical Society. All rights reserved.

引用

页码：2642 / +

页数：1

共 27 条

[1] THE ULTRA-VIOLET ABSORPTION SPECTRA OF SODIUM HYPONITRITE AND SODIUM ALPHA-OXYHYPONITRITE - THE ANALYSIS OF MIXTURES WITH SODIUM NITRITE AND NITRATE [J].

ADDISON, CC ;

GAMLEN, GA ;

THOMPSON, R .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (FEB) :338-345

[2] CRYSTAL STRUCTURE OF BLACK NITROSYLPENTAMMINECOBALT DICHLORIDE [J].

DALE, D ;

HODGKIN, DC .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (FEB) :1364-&

[3] INFRARED SPECTRUM OF SODIUM ALPHA-OXYHYPONITRITE [J].

FELTHAM, RD .

INORGANIC CHEMISTRY, 1964, 3 (06) :900-&

[4] CRYSTAL STRUCTURE OF NITROSYLPENTAMMINECOBALT DICHLORIDE ( BLACK FORM ) [J].

HALL, D ;

TAGGART, AA .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (FEB) :1359-&

[5] STRUCTURE OF OXHYPONITRITE ION [J].

HENDRICKSON, DN ;

JOLLY, WL .

INORGANIC CHEMISTRY, 1969, 8 (03) :693-+

[6] ELECTRONEGATIVITY .1. ORBITAL ELECTRONEGATIVITY OF NEUTRAL ATOMS [J].

HINZE, J ;

JAFFE, HH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (04) :540-&

[7] AN EXTENDED HUCKEL THEORY .I. HYDROCARBONS [J].

HOFFMANN, R .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (06) :1397-&

[8] NITROGEN 1S ELECTRON BINDING ENERGIES . CORRELATION WITH CNDO CHARGES [J].

HOLLANDER, JM ;

HENDRICKSON, DN ;

JOLLY, WL .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (07) :3315-+

[9]

HOLLANDER JM, 1965, ARK FYS, V28, P375

[10] HEAT OF FORMATION OF CRYSTALLINE SODIUM ALPHA-OXYHYPONITRITE - STRUCTURE OF AQUEOUS ALPHA-OXYHYPONITRITE ION [J].

HUNT, HR ;

COX, JR ;

RAY, JD .

INORGANIC CHEMISTRY, 1962, 1 (04) :938-&

← 1 2 3 →