ANALYSIS OF EPR POWDER PATTERN LINESHAPES FOR MN(II) INCLUDING 3RD-ORDER PERTURBATION CORRECTIONS - APPLICATIONS TO MN(II) COMPLEXES WITH ENZYMES

被引：30

作者：

MARKHAM, GD

RAO, BDN

REED, GH

机构：

[1] The University of Pennsylvania, Philadelphia

来源：

JOURNAL OF MAGNETIC RESONANCE | 1979年 / 33卷 / 03期

关键词：

D O I：

10.1016/0022-2364(79)90171-9

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Third-order perturbation theory is used to obtain expressions for the energy levels of 55Mn(II)(I = 5 2; S = 5 2) in the presence of an external magnetic field with axial and rhombic distortions in the crystal field. The expressions are used to stimulate line shapes for the central ( 1 2↔- 1 2) fine structure transition in the EPR spectra for Mn(II) in complexes with enzymes. © 1979.

引用

页码：595 / 602

页数：8

共 15 条

[1]

BUTTLAIRE DH, 1975, J BIOL CHEM, V250, P261

[2]

Condon E. U., 1951, THEORY ATOMIC SPECTR

[3] ELECTRON SPIN RESONANCE OF MANGANESE IN BORATE GLASSES [J].