WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .2. CATALYTIC-HYDROGENATION OF ALDEHYDES AND OLEFINS BY NEW WATER-SOLUBLE 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEXES OF RUTHENIUM AND RHODIUM

被引：143

作者：

DARENSBOURG, DJ ^{[1
]}

JOO, F ^{[1
]}

KANNISTO, M ^{[1
]}

KATHO, A ^{[1
]}

REIBENSPIES, JH ^{[1
]}

机构：

[1] LAJOS KOSSUTH UNIV,INST PHYS CHEM,H-4010 DEBRECEN,HUNGARY

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 06期

关键词：

D O I：

10.1021/om00042a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Water-soluble phosphine complexes of ruthenium(II) and rhodium(I) have been prepared by the reduction of RuCl3 and RhCl3 in ethanol in the presence of the air-stable phosphine 1,3,5-triaza-7-phosphaadamantane (1). The complex RuCl2(PTA)4 (2a) and its protonated analog RuCl2(PTA)4-2HCl (2b) have been characterized by X-ray crystallography. Similarly, the cis-bis-(phosphine) complex RhCl(PTA)2.2HCl, derived from the protonation of RhCl(PTA)3 by HCl, has been characterized by X-ray crystallography. The water-soluble ruthenium phosphine derivative 2a is catalytically quite active for the conversion of unsaturated aldehydes to unsaturated alcohols using a biphasic aqueous/organic medium with formate as the source of hydrogen. By way of contrast, under similar conditions RhCl(PTA)3 is a very active catalyst for olefin hydrogenation.

引用

页码：1990 / 1993

页数：4

共 36 条

[1] CHIRAL SULFONATED PHOSPHINES - SYNTHESES AND USE AS LIGANDS IN ASYMMETRIC HYDROGENATION USING AN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEM
AMRANI, Y
LECOMTE, L
SINOU, D
BAKOS, J
TOTH, I
HEIL, B
[J]. ORGANOMETALLICS, 1989, 8 (02) : 542 - 547
[2] ORGANOMETALLIC CATALYSIS IN AQUEOUS-SOLUTIONS - THE BIPHASIC TRANSFER HYDROGENATION OF ALDEHYDES CATALYZED BY WATER-SOLUBLE PHOSPHINE COMPLEXES OF RUTHENIUM, RHODIUM AND IRIDIUM
BENYEI, A
JOO, F
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1990, 58 (02): : 151 - 163
[3] BOROWSKI AF, 1978, NOUV J CHIM, V2, P137
[4] PALLADIUM-CATALYZED ALKYLATIONS IN AQUEOUS-MEDIA
CASALNUOVO, AL
CALABRESE, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) : 4324 - 4330
[5] COTTON FA, 1988, ADV INORG CHEM, pCH19
[6] DAIGLE DJ, 1974, J HETEROCYCLIC CHEM, V17, P407
[7] SYNTHESIS AND SPECTRAL PROPERTIES OF METAL-CARBONYL DERIVATIVES OF TETRABASIC, NONCHELATING PHOSPHATRIAZAADAMANTANE LIGAND
DARENSBOURG, MY
DAIGLE, D
[J]. INORGANIC CHEMISTRY, 1975, 14 (05) : 1217 - 1218
[8] MOLECULAR-STRUCTURE AND SPECTRAL PROPERTIES OF PHOSPHATRIAZAADAMANTANEMOLYBDENUM PENTACARBONYL COMPLEX
DELERNO, JR
TREFONAS, LM
DARENSBOURG, MY
MAJESTE, RJ
[J]. INORGANIC CHEMISTRY, 1976, 15 (04) : 816 - 819
[9] A P-31 NMR-STUDY OF THE WATER-SOLUBLE DERIVATIVES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (PTA)
FISHER, KJ
ALYEA, EC
SHAHNAZARIAN, N
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1990, 48 (1-4): : 37 - 40
[10] FLUCK E, 1977, Z NATURFORSCH B, V32, P499

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