SYNTHESIS AND DYNAMIC STEREOCHEMISTRY OF A TRI(1-AZULENYL)METHYL CATION CONTAINING A DIFFERENT SUBSTITUENT ON EACH AZULENE RING

被引：19

作者：

ITO, S ^{[1
]}

MORITA, N ^{[1
]}

ASAO, T ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, AOBA KU, SENDAI, MIYAGI 98077, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 07期

关键词：

D O I：

10.1246/bcsj.68.2011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of a tri(1-azulenyl)methyl cation (2) containing a different substituent on each azulene ring was synthesized, and the dynamic stereochemistry was studied by temperature-dependent H-1 NMR spectra. The dynamic behavior of 2 supported a one-ring hip mechanism and the validity of the hip mechanism for the analysis of the conformational change of the tri(1-azulenyl) methyl cations.

引用

页码：2011 / 2016

页数：6

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