A SEMICLASSICAL CORRELATION-FUNCTION APPROACH TO BARRIER TUNNELING

被引:83
作者
GROSSMANN, F
HELLER, EJ
机构
[1] HARVARD UNIV,DEPT PHYS,CAMBRIDGE,MA 02138
[2] HARVARD UNIV,HARVARD SMITHSONIAN CTR ASTROPHYS,CAMBRIDGE,MA 02138
关键词
D O I
10.1016/0009-2614(95)00605-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A time domain approach employing the semiclassical approximation to the quantum mechanical propagator, as applied to Gaussian wavepackets, is used to study the barrier penetration problem. We have observed that qualitative agreement with the exact quantum calculations for the correlation function and the transmission probability can be achieved by considering only classically allowed trajectories. The results slowly tend to the classical step function at the barrier top as a function of the wavepacket center parameter, however. We suggest that a full semiclassical calculation, including nonclassical trajectories with complex energies, would improve the results.
引用
收藏
页码:45 / 50
页数:6
相关论文
共 14 条
[1]  
Brink D.M., 1985, SEMICLASSICAL METHOD
[2]   The penetration of a potential barrier by electrons [J].
Eckart, C .
PHYSICAL REVIEW, 1930, 35 (11) :1303-1309
[3]  
FEIT MD, 1983, J COMPUT PHYS, V47, P412
[4]   CLASSICAL S-MATRIX THEORY OF REACTIVE TUNNELING - LINEAR H+H2 COLLISIONS [J].
GEORGE, TF ;
MILLER, WH .
JOURNAL OF CHEMICAL PHYSICS, 1972, 57 (06) :2458-&
[5]   PHASE-INTEGRAL APPROXIMATION IN MOMENTUM SPACE AND BOUND STATES OF AN ATOM [J].
GUTZWILLER, MC .
JOURNAL OF MATHEMATICAL PHYSICS, 1967, 8 (10) :1979-+
[6]   CELLULAR-DYNAMICS - A NEW SEMICLASSICAL APPROACH TO TIME-DEPENDENT QUANTUM-MECHANICS [J].
HELLER, EJ .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (04) :2723-2729
[7]   TIME-DEPENDENT APPROACH TO SEMICLASSICAL DYNAMICS [J].
HELLER, EJ .
JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (04) :1544-1555
[8]   BARRIER PENETRATION VIA PATH-INTEGRALS [J].
HOLSTEIN, BR ;
SWIFT, AR .
AMERICAN JOURNAL OF PHYSICS, 1982, 50 (09) :833-839
[9]   SEMICLASSICAL CORRECTION FOR QUANTUM-MECHANICAL SCATTERING [J].
KESHAVAMURTHY, S ;
MILLER, WH .
CHEMICAL PHYSICS LETTERS, 1994, 218 (03) :189-194
[10]  
Maslov V. P., 1981, SEMICLASSICAL APPROX