THERMODYNAMICS AND PHASE-BEHAVIOR OF LIQUID-CRYSTALLINE

被引：6

作者：

BALLAUFF, M

机构：

[1] Polymer-Institut, Universität Karlsruhe, 7500 Karlsruhe

来源：

FLUID PHASE EQUILIBRIA | 1993年 / 83卷

关键词：

LIQUID CRYSTALLINE POLYMERS; MESOPHASES; FLORY LATTICE MODEL;

D O I：

10.1016/0378-3812(93)87038-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The phase behaviour of stiff-chain polyesters bearing flexible side chains is presented and compared to model calculations on the base of the Flory lattice model. The factors governing the stability of the various ordered phases is discussed. It is shown that the high nematic-to-isotropic transition temperatures are in qualitative agreement with theory.

引用

页码：349 / 355

页数：7

共 14 条

[1]

ABE A, 1991, LIQUID CRYSTAL POLYM

[2]

ADAM A, 1990, MAKROMOL CHEM-RAPID, V11, P249

[3] RIGID ROD POLYMERS HAVING FLEXIBLE SIDE-CHAINS .3. STRUCTURAL INVESTIGATIONS ON A NOVEL LAYERED MESOPHASE FORMED BY THERMOTROPIC POLY(1,4-PHENYLENE-2,5-DIALKOXY TEREPHTHALATE)S [J].