TIO2-BASED VITREOUS COATINGS OBTAINED BY SOL-GEL METHOD

被引：21

作者：

ZAHARESCU, M ^{[1
]}

PIRLOG, C ^{[1
]}

CRISAN, M ^{[1
]}

GARTNER, M ^{[1
]}

VASILESCU, A ^{[1
]}

机构：

[1] ACAD ROMANA,INST PHYS CHEM,SPL INDEPENDENTEI 202,R-77208 BUCHAREST,ROMANIA

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1993年 / 160卷 / 1-2期

关键词：

D O I：

10.1016/0022-3093(93)90296-A

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

TiO2 films and TiO2 films incorporating cobalt and copper ions by the sol-gel method were investigated. Undoped TiO2 films crystallize to anatase above 300-degrees-C. Cu2+ and Co2+ inhibit the crystallization of anatase with Cu having a stronger influence then Co. Cu2+ introduced in the lattice has a square planar coordination in TiO2 matrix while Co2+ has a octahedral coordination. These films are coloured thus the optical properties of TiO2 films can be strongly modulated by the incorporation of a transition metal ion.

引用

页码：162 / 166

页数：5

共 20 条

[1] DIP-COATED TIO2-CEO2 FILMS AS TRANSPARENT COUNTERELECTRODE FOR TRANSMISSIVE ELECTROCHROMIC DEVICES [J].

BAUDRY, P ;

RODRIGUES, ACM ;

AEGERTER, MA ;

BULHOES, LO .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 121 (1-3) :319-322

[2] AMORPHOUS AND CRYSTALLINE DIP COATINGS OBTAINED FROM ORGANOMETALLIC SOLUTIONS - PROCEDURES, CHEMICAL PROCESSES AND PRODUCTS [J].

DISLICH, H ;

HUSSMANN, E .

THIN SOLID FILMS, 1981, 77 (1-3) :129-139

[3] GLASSY AND CRYSTALLINE SYSTEMS FROM GELS, CHEMICAL BASIS AND TECHNICAL APPLICATION [J].

DISLICH, H .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1984, 63 (1-2) :237-241

[4] THE GEL ROUTE TO CR3+-DOPED TIO2, AN ELECTRON-SPIN-RESONANCE STUDY [J].

DOEUFF, S ;

HENRY, M ;

SANCHEZ, C ;

LIVAGE, J .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 89 (1-2) :84-97

[5] SILICA AND SILICA-TITANIA GLASSES PREPARED BY THE SOL-GEL PROCESS [J].

GONZALEZOLIVER, CJR ;

JAMES, PF ;

RAWSON, H .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1982, 48 (01) :129-152

[6]

KLUG HP, 1959, XRAY DIFFRACTION PRO, P491

[7] PREPARATION AND CHARACTERIZATION OF THIN-FILMS OF TIO2-PBO AND TIO2-BI2O3 COMPOSITIONS [J].

LASERRA, ER ;

CHARBOUILLOT, Y ;

BAUDRY, P ;

AEGERTER, MA .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 121 (1-3) :323-328

[8]

LEVER BP, 1987, INORGANIC ELECTRONIC, P214

[9] PREPARATION AND PROPERTIES OF TIO2-CEO2 COATINGS BY THE SOL-GEL PROCESS [J].

MAKISHIMA, A ;

ASAMI, M ;

WADA, K .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 121 (1-3) :310-314

[10] PREPARATION OF CEO2-TIO2 COATINGS BY THE SOL-GEL PROCESS [J].

MAKISHIMA, A ;

ASAMI, M ;

WADA, K .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 100 (1-3) :321-324

← 1 2 →