DIASTEREOSELECTIVE SYNTHESIS OF EXO-6-ARYL-3-AZABICYCLO[3.2.0]HEPTANE DERIVATIVES BY INTRAMOLECULAR [2+2]-PHOTOCYCLOADDITIONS OF DIALLYLIC AMINES

被引：19

作者：

STEINER, G ^{[1
]}

MUNSCHAUER, R ^{[1
]}

KLEBE, G ^{[1
]}

SIGGEL, L ^{[1
]}

机构：

[1] BASF AG,CENT INFORMAT,D-67056 LUDWIGSHAFEN,GERMANY

来源：

HETEROCYCLES | 1995年 / 40卷 / 01期

关键词：

D O I：

10.3987/COM-94-S34

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Cinnamyl-N-allylamines (1) react upon irradiation with UV light via a photochemical [2+2] cycloaddition to give new exo-6-aryl-3-azabicyclo[3.2.0]heptanes (2) with high diastereoselectivity. A kinetic study as well as semiempirical quantum mechanical calculations support the proposed mechanism.

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页码：319 / 330

页数：12

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