MOSSBAUER INVESTIGATION OF IRON SPECIES IN A ZEOLITE

被引：6

作者：

WEDD, RWJ

LIENGME, BV

SCOTT, JC

SAMS, JR

机构：

[1] Department of Chemistry, University of British Columbia, Vancouver 8, BC

来源：

SOLID STATE COMMUNICATIONS | 1969年 / 7卷 / 15期

关键词：

D O I：

10.1016/0038-1098(69)90478-5

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Fe3+ ions and molecular FeCl3 have been introduced into Linde L-zeolite. Outgassing at 300° produces a mixture of Fe3+ and Fe2+ species. Reduction in H2 at 350° yields metallic iron and a Fe2+ species. The Fe° shows Zeeman splitting (hence is on exterior surfaces) and a Morin transition. Pumping the reduced sample at 350° produces Fe2O3, the Fe2+ species remaining unaltered. © 1969.

引用

页码：1091 / &

共 6 条

[1]

BARRER RM, 1958, STRUCTURE PROPERTIES

[2]

Breck D.W., 1964, J CHEM EDUC, V41, P678, DOI [10.1021/ed041p678, DOI 10.1021/ED041P678]

[3] A MOSSBAUER STUDY OF GRAPHITE IRON CHLORIDE COMPOUNDS [J].

HOOLEY, JG ;

BARTLETT, MW ;

LIENGME, BV ;

SAMS, JR .

CARBON, 1968, 6 (05) :681-&

[4]

LIENGME BV, 1967, PHYS LETT A, V24, P127

[5] MOSSBAUER STUDIES OF 57FE IN ZEOLITES [J].

MORICE, JA ;

REES, LVC .

TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (545P) :1388-+

[6]

Rabo J. A., 1964, Decationized Molecular Sieve Compositions, Patent No. [US3130006, 3130006]

← 1 →