BISPHOSPHONIC COMPOUNDS .2. PREPARATION OF MONOPHOSPHONIC STARTING MATERIALS - MIXED ESTERS OF METHYLPHOSPHONIC ACID

被引：4

作者：

JOUKO, V ^{[1
]}

HEIKKI, N ^{[1
]}

ESKO, P ^{[1
]}

机构：

[1] HUHTAMAKI OY LEIRAS, SF-33721 TAMPERE, FINLAND

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 02期

关键词：

D O I：

10.1080/00397919208021302

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl (1-methylethyl) methylphosphonate was obtained from PCl3 via (Pr(i)O)PCl2 and (Pr(i)O)P(OMe)2 followed by the Michaelis-Arbuzov reaction with Mel. The yield was 79 % with 95 % chemical purity. Less reasonable conversions were obtained for some related mixed diesters.

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页码：271 / 276

页数：6

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