The Infrared Absorption Spectrum of Water Containing Deuterium

被引：38

作者：

Ellis, Joseph W. ^{[1
]}

Sorge, Barthold W. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Los Angeles, CA 90024 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1934年 / 2卷 / 09期

关键词：

D O I：

10.1063/1.1749531

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Absorption percentages for the region 1-10 mu are presented for one sample of water, 60 percent of whose hydrogen is deuterium, and for a second sample containing 99.5 percent deuterium oxide. Maxima are picked out as the three fundamental frequencies for the molecules DOD and HOD. These are compared with values predicted by an isotopic shift calculation based on data chosen from the spectrum of ordinary water. All other higher frequency maxima are interpreted as overtones or combination bands, but only after a fourth fundamental frequency is chosen in the examples of HOH and DOD.

引用

页数：6