SYNTHESIS OF ASYMMETRIC SECONDARY AND TERTIARY-AMINES FROM A PRIMARY AMINE AND ALCOHOL OVER THE METHANOL SYNTHESIS INDUSTRIAL CATALYST SNM-1

被引：1

作者：

SHUIKIN, AN

GLEBOV, LS

KLIGER, GA

ZAIKIN, VG

机构：

[1] A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 117912

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 04期

关键词：

AMINATION; CATALYTIC; ALKANOLS; AMINES; PRIMARY; SECONDARY; TERTIARY; COPPER-CONTAINING CATALYST;

D O I：

10.1007/BF00704025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vapor-phase reactions of n-pentan-1-ol with 2-ethylhexylamine and of n-heptan-1-ol with cyclohexylamine occurring in the presence of an industrial oxide copper-zinc-aluminnum catalyst SNM-1 at 175-185-degrees-C have been found to afford the corresponding asymmetric secondary and tertiary amines in yields of 59-99 % and 5-49 %, respectively.

引用

页码：768 / 770

页数：3