EXTRACTIVE-SPECTROPHOTOMETRIC METHOD FOR THE DETERMINATION OF PALLADIUM USING THIOSALICYLIC ACID AND HEXYLAMINE

被引：15

作者：

CHHAKKAR, AK ^{[1
]}

KAKKAR, LR ^{[1
]}

机构：

[1] KURUKSHETRA UNIV,DEPT CHEM,KURUKSHETRA 132119,HARYANA,INDIA

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1993年 / 347卷 / 12期

关键词：

D O I：

10.1007/BF00324239

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A highly sensitive and selective spectrophotometric method for the determination of palladium has been worked out in neutral medium utilizing thiosalicylic acid as a ligand. The coloured metal complex thus obtained is quantitatively extractable into chloroform in the presence of hexylamine. The method is free from the interference of a large number of metal ions including platinum metals. The ratio of metal to ligand in the extracted species is 1:2. The standard deviation is +/- 0.002.

引用

页码：483 / 485

页数：3

共 19 条

[1]

BUSEV AI, 1958, VESTN MOSKOV U, V4, P179

[2]

DEMA I, 1960, ACAD REP POPULARE RO, V8, P173

[3] SPECTROPHOTOMETRIC DETERMINATION OF PALLADIUM WITH THIOGLYCOLIC ACID [J].

DIAMANTATOS, A .

ANALYTICA CHIMICA ACTA, 1972, 61 (02) :233-+

[4]

HERNANDEZ MJ, 1987, MICROCHEM J, V35, P7

[5]

IVANOV VM, 1972, IND LAB-USSR+, V38, P1311

[6] PALLADIUM(2) COMPLEX OF PICOLINEALDEHYDE 2-QUINOLYLHYDRAZONE [J].

JENSEN, RE ;

PFLAUM, RT .

ANALYTICA CHIMICA ACTA, 1967, 37 (03) :397-&

[7]

Job P, 1928, ANN CHIM FRANCE, V9, P113

[8]

JOHN HY, 1954, ANAL CHEM, V26, P1335

[9] EXTRACTIVE SPECTROPHOTOMETRIC DETERMINATION OF PALLADIUM(II) AND PLATINUM(II) WITH 2-ALLYLTHIOUREA AND THIOCYANATE IN THE PRESENCE OF EDTA [J].

KAVLENTIS, E .

MICROCHEMICAL JOURNAL, 1987, 36 (03) :306-308

[10]

LYSTSOVA GG, 1962, ZAVODSK LAB, V28, P543

← 1 2 →