A RESOLUTION OF MONODENTATE P-ASTERISK CHIRAL PHOSPHINE

被引：57

作者：

DUNINA, VV

GOLOVAN, EB

机构：

[1] Department of Chemistry, M. V. Lomonosov Moscow State University, 119899, V-234, Moscow

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 11期

关键词：

D O I：

10.1016/0957-4166(95)00364-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The monodentate phosphine PMeBu(t)Ph is obtained in enantiopure form by using a new N*-chiral ortho-palladated resolving agent; some advantages of the latter over its N-achiral analogue are shown. The conditions of resolved phosphine displacement from individual diastereomers of palladium(II) complexes are elaborated which allow the starting resolving agent to be recovered.

引用

页码：2747 / 2754

页数：8

共 33 条

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