SYNTHESES AND PROPERTIES OF FERROCENYLETHYNYL TRANSITION-METAL COMPLEXES OF PLATINUM, PALLADIUM, AND NICKEL

被引：11

作者：

ONITSUKA, K ^{[1
]}

TAO, XQ ^{[1
]}

SONOGASHIRA, K ^{[1
]}

机构：

[1] OSAKA CITY UNIV, FAC ENGN, DEPT APPL CHEM, SUMIYOSHI KU, OSAKA 558, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 09期

关键词：

D O I：

10.1246/bcsj.67.2611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Square planar ferrocenylethynyl transition metal complexes M(C=CFc)2(PR3)2 (M = Pt, Pd, Ni; Fc = (C5H4)Fe(C5H5)) were prepared by the reaction of MCl2(PR3)2 with ethynylferrocene in the presence of a CuI catalyst in diethylamine, and characterized by spectral analyses. An interaction between transition metals and an iron atom was studied by using electronic spectroscopy.

引用

页码：2611 / 2613

页数：3

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