REGIOSELECTIVE SYNTHESIS OF TERMINAL OLEFINS FROM ALKANES VIA RHODIUM-CATALYZED C-H ACTIVATION

被引：31

作者：

SAKAKURA, T ^{[1
]}

HAYASHI, T ^{[1
]}

TANAKA, M ^{[1
]}

机构：

[1] NATL CHEM LAB IND, YATABE, IBARAKI 305, JAPAN

来源：

CHEMISTRY LETTERS | 1987年 / 05期

关键词：

D O I：

10.1246/cl.1987.859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：859 / 862

页数：4

共 11 条

[1] THERMAL AND PHOTOCHEMICAL CATALYTIC DEHYDROGENATION OF ALKANES WITH [IRH2(CF3CO2)(PR3)2] (R = C6H4F-P AND CYCLOHEXYL) [J].

BURK, MJ ;

CRABTREE, RH ;

MCGRATH, DV .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (24) :1829-1830

[2]

Calvert J., 1967, PHOTOCHEMISTRY

[3] THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1985, 85 (04) :245-269

[4] ACTIVATION OF C-H BONDS IN SATURATED-HYDROCARBONS - THE SELECTIVE, CATALYTIC FUNCTIONALIZATION OF METHYL-GROUPS BY MEANS OF A SOLUBLE IRIDIUM POLYHYDRIDE SYSTEM [J].

FELKIN, H ;

FILLEBEENKHAN, T ;

HOLMESSMITH, R ;

YINGRUI, L .

TETRAHEDRON LETTERS, 1985, 26 (16) :1999-2000

[5] OXIDATIVE ADDITION OF SOLUBLE IRIDIUM AND RHODIUM COMPLEXES TO CARBON-HYDROGEN BONDS IN METHANE AND HIGHER ALKANES [J].

JANOWICZ, AH ;

PERIANA, RA ;

BUCHANAN, JM ;

KOVAC, CA ;

STRYKER, JM ;

WAX, MJ ;

BERGMAN, RG .

PURE AND APPLIED CHEMISTRY, 1984, 56 (01) :13-23

[6] ACTIVATION OF C-H-BONDS IN SATURATED-HYDROCARBONS ON PHOTOLYSIS OF (ETA-5-C5ME5)(PME3)IRH2 - RELATIVE RATES OF REACTION OF THE INTERMEDIATE WITH DIFFERENT TYPES OF C-H-BONDS AND FUNCTIONALIZATION OF THE METAL-BOUND ALKYL-GROUPS [J].

JANOWICZ, AH ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) :3929-3939

[7] THE MECHANISM AND THERMODYNAMICS OF ALKANE AND ARENE CARBON-HYDROGEN BOND ACTIVATION IN (C5ME5)RH(PME3)(R)H [J].

JONES, WD ;

FEHER, FJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (06) :1650-1663

[8] EFFICIENTLY CATALYTIC C-H ACTIVATION - DIRECT AND MILD CARBONYLATION OF BENZENE AND CYCLOHEXANE BY RHCL(CO)(PME3)2 UNDER IRRADIATION [J].

SAKAKURA, T ;

TANAKA, M .

CHEMISTRY LETTERS, 1987, (02) :249-252

[9]

SAKAKURA T, UNPUB

[10]

Shilov A. E., 1984, ACTIVATION SATURATED

← 1 2 →