EXISTENCE OF A NEW C6H6 ISOMER - TRICYCLO[3.1.0.02,6]HEX-1(6)-ENE

被引：70

作者：

SZEIMIESSEEBACH, U ^{[1
]}

VANMEERSSCHE, M ^{[1
]}

GERMAIN, G ^{[1
]}

DECLERQ, JP ^{[1
]}

SZEIMIES, G ^{[1
]}

HARNISCH, J ^{[1
]}

机构：

[1] CATHOLIC UNIV LOUVAIN,CHIM PHYS & CRISTALLOGR LAB,B-1348 LOUVAIN LA NEUVE,BELGIUM

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1978年 / 17卷 / 11期

关键词：

D O I：

10.1002/anie.197808481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

“Isobenzvalene” 1, a very highly strained molecule, has now been trapped in the form of the Diels‐Alder adduct 2 with anthracene. The structure of 2 is also unusual: C‐11 and C‐16 are both located outside the tetrahedron formed by their four substituents (“inverted tetrahedron”). (Figure Presented.) Copyright © 1978 by Verlag Chemie, GmbH, Germany

引用

页码：848 / 850

页数：3

共 14 条

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