DETERMINATION OF THE SURFACE FREE-ENERGY OF MODIFIED CARBON-FIBERS AND ITS RELATION TO THE WORK OF ADHESION

被引：37

作者：

TSUTSUMI, K ^{[1
]}

ISHIDA, S ^{[1
]}

SHIBATA, K ^{[1
]}

机构：

[1] CHUBU UNIV, KASUGAI, AICHI 487, JAPAN

来源：

COLLOID AND POLYMER SCIENCE | 1990年 / 268卷 / 01期

关键词：

ESCA; modified carbon fibers; Surface free energy; tensiometry; work of adhesion;

D O I：

10.1007/BF01410420

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Surface free energy of various carbon fibers was determined by tensiometric method in three different procedures. The dispersive γsd and the nondispersive γsp components were separately determined by contact angle measurements in two-phase system, formamide-n-alkanes. The γsp increased by oxidation and decreased by hydrogen reduction, while the γsd remained almost constant.The γsp value determined from contact angle of water/ethyleneglycol solution tended to become higher. The critical surface free energy was in harmony with the total free energy determined from formamide-n-alkanes system as long as liquids were properly selected. The formation of oxygen-containing functional groups was evidenced by ESCA, and the surface [O]/[C] ratio was related linearly to the surface polarity defined by γsp[γsd+γsp] Oxidation in liquid phase resulted in the formation of both hydroxyls and carboxyls, while only hydroxyls were formed in gas phase. The interfacial shear strength of the fiber-epoxy resin could be closely correlated with thermodynamical work of adhesion calculated on the basis of surface free energy and its component. © 1990 Steinkopff.

引用

页码：31 / 37

页数：7

共 31 条

[1] ADHESION OF HYDROPHILIC PARTICLES TO POLYMER SUBSTRATES IMMERSED IN AQUEOUS-MEDIA [J].