ASYMMETRIC ALDOL REACTION - A HIGHLY ERYTHRO-SELECTIVE ALDOL REACTION BETWEEN TRICARBONYL(ORTHO-TRIMETHYLSILYLBENZALDEHYDE DERIVATIVE)-CHROMIUM(0) COMPLEXES AND CYCLIC SILYL ENOL ETHERS

被引：46

作者：

MUKAI, C

CHO, WJ

KIM, IJ

KIDO, M

HANAOKA, M

机构：

[1] KANAZAWA UNIV,FAC PHARMACEUT SCI,KANAZAWA,ISHIKAWA 920,JAPAN

[2] OTSUKA PHARMACEUT CO LTD,TOKUSHIMA INST NEW DRUG RES 2,TOKUSHIMA 77101,JAPAN

来源：

TETRAHEDRON | 1991年 / 47卷 / 18-19期

关键词：

D O I：

10.1016/S0040-4020(01)96032-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of (+/-)-chromium (0)-complexes 4e-g with 5-7 gave the erythro isomers in a highly selective manner. This aldol reaction was successfully applied to the asymmetric one. The absolute configuration was determined by X-ray analysis of (-)-erythro-8e.

引用

页码：3007 / 3036

页数：30

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