ENERGETICS OF COBALT(II) OXIDE WITH THE ZINCBLENDE STRUCTURE

被引：16

作者：

DICARLO, J ^{[1
]}

NAVROTSKY, A ^{[1
]}

机构：

[1] PRINCETON UNIV,PRINCETON MAT INST,PRINCETON,NJ 08544

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1993年 / 76卷 / 10期

关键词：

D O I：

10.1111/j.1151-2916.1993.tb03967.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Cobalt(II) oxide (CoO) has been prepared in the zinc-blende structure by the decomposition of cobalt(II) acetate under vacuum at 290-degrees-C. Calorimetric experiments have shown that the zinc-blende structure is energetically 37 +/-10 kJ/mol less stable than the common rock-salt form of CoO. This value is in good agreement with the value recently reported by Grimes and Lagerlof of 38 kJ/mol found by a lattice energy calculation.

引用

页码：2465 / 2467

页数：3

共 10 条

[1] ENERGETICS OF LA2-XSRXCUO4-Y SOLID-SOLUTIONS (0.0-LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-1.0) [J].