CYCLOADDITION REACTIONS OF STABLE SILENES WITH ACYLSILANES

被引：9

作者：

BROOK, AG

KUMARATHASAN, R

CHATTERTON, W

机构：

[1] Lash Miller Chemical Laboratories, University of Toronto

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1021/om00034a049

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silenes of the family (Me3Si)2Si=C(OSiMe3)R (R = Ad, t-Bu, Mes) generally react with the simple aroylsilanes R'3SiCOAr (R' = Ph, Me; Ar = Ph, C6H4-X-P) in a [2 + 4] manner to give relatively stable bicyclic adducts. Only the [2 + 2] adduct was formed when R = Mes, R' = Me3Si, and Ar = Ph. The H-1, C-13, and Si-29 NMR spectral data for a series of simple acylsilanes Ph3SiCOC6H4X-p and Me3SiCOPh are given.

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页码：4085 / 4089

页数：5

相关论文

共 18 条

[1] SUBSTITUENT EFFECTS ON THE CARBON SILICON DOUBLE-BOND - MONOSUBSTITUTED SILENES [J].

APELOIG, Y ;

KARNI, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) :6676-6682

[2]

AUNER N, 1990, Z NATURFORSCH B, V45, P909

[3] PHOTOCHEMICAL REARRANGEMENTS OF STABLE SILENES [J].

BAINES, KM ;

BROOK, AG ;

FORD, RR ;

LICKISS, PD ;

SAXENA, AK ;

CHATTERTON, WJ ;

SAWYER, JF ;

BEHNAM, BA .

ORGANOMETALLICS, 1989, 8 (03) :693-709

[4] SPECTRAL PROPERTIES OF P-SUBSTITUTED BENZOYLTRIPHENYLSILANES [J].

BROOK, AG ;

KIVISIKK, R ;

LEGROW, GE .

CANADIAN JOURNAL OF CHEMISTRY, 1965, 43 (05) :1175-&

[5] REACTIONS OF SILENES WITH ALPHA,BETA-UNSATURATED ALDEHYDES AND KETONES [J].

BROOK, AG ;

HU, SS ;

CHATTERTON, WJ ;

LOUGH, AJ .

ORGANOMETALLICS, 1991, 10 (08) :2752-2757

[6] PHOTOCHEMISTRY OF ACYLDISILANES [J].

BROOK, AG ;

BAUMEGGER, A ;

LOUGH, AJ .

ORGANOMETALLICS, 1992, 11 (01) :310-317

[7] CYCLOADDITION AND OTHER REACTIONS OF SILENES WITH ALPHA,BETA-UNSATURATED ESTERS [J].

BROOK, AG ;

HU, SS ;

SAXENA, AK ;

LOUGH, AJ .

ORGANOMETALLICS, 1991, 10 (08) :2758-2767

[8] SI-29 NMR-STUDIES OF RELATIVELY STABLE SILAETHYLENES [J].

BROOK, AG ;

NYBURG, SC ;

REYNOLDS, WF ;

POON, YC ;

CHANG, YM ;

LEE, JS ;

PICARD, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (22) :6750-6752

[9] THE SPECTRAL AND CHEMICAL PROPERTIES OF ALPHA-SILYL KETONES [J].

BROOK, AG ;

QUIGLEY, MA ;

PEDDLE, GJD ;

SCHWARTZ, NV ;

WARNER, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (19) :5102-5106

[10] 1,2-SILOXETANES - FORMATION, STRUCTURE, AND REARRANGEMENTS [J].

BROOK, AG ;

CHATTERTON, WJ ;

SAWYER, JF ;

HUGHES, DW ;

VORSPOHL, K .

ORGANOMETALLICS, 1987, 6 (06) :1246-1256