SYNTHETIC STUDIES TOWARD CIGUATOXIN - STEREOCONTROLLED CONSTRUCTION OF THE KLM RING FRAGMENT

被引：65

作者：

SASAKI, M ^{[1
]}

INOUE, M ^{[1
]}

TACHIBANA, K ^{[1
]}

机构：

[1] UNIV TOKYO,SCH SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 04期

关键词：

D O I：

10.1021/jo00083a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first stereoselective synthesis of the KLM ring fragment of ciguatoxin is reported including as a key step 7-endo selective cyclization of epoxy alcohol to construct a fully substituted oxepane ring (12 --> 13).

引用

页码：715 / 717

页数：3

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