SYNTHESIS AND STRUCTURE OF A HYDRIDE-BRIDGED AND SULFIDE-BRIDGED TETRANUCLEAR RUTHENIUM(II,III) CLUSTER COMPLEX

被引：9

作者：

MATSUMOTO, K

OHNUKI, H

KAWANO, M

机构：

[1] Department of Chemistry, Waseda University, Okubo, Shinjuku-ku

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 14期

关键词：

D O I：

10.1021/ic00118a039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The sulfide- and hydride-bridged mixed-valent Ru(II,III) complex [Ru-4(P(OMe)(3))(8)(mu(2)-H)(2)(mu(2)-S)(2)(mu(4)-S)(2)] has been synthesized from the reduction of [{Ru(AN)-(P(OMe)(3))(2)}(2)(mu-Cl)(2)(mu-S-2)](CF3SO3)(2) (AN is CH3CN) with Mg powder in methanol, and the crystal structure has been solved with single-crystal X-ray diffraction technique.

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页码：3838 / 3840

页数：3

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共 22 条

[1] CLUSTER SYNTHESIS .26. CONDENSATION OF RU3(CO)9(MU-3-MEC2NME2)(MU-3-S) TO RU6(CO)14(MU-3-MEC2NME2)2(MU-4-S)2 AND RU6(CO)13(MU-MEC2NME2)(MU-3-MEC2NME2)(MU-4-S)2 [J].

ADAMS, RD ;

CHEN, G ;

TANNER, JT ;

YIN, JG .

ORGANOMETALLICS, 1990, 9 (04) :1240-1245

[2] OXIDATIVE CLEAVAGE OF METAL-METAL BONDS IN HETERONUCLEAR CLUSTERS - REACTION OF SNCL4 WITH (MU-H)2(MU-3-S)RU3(CO)9 AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF (MU-H)2(MU-3-S)RU3(CO)9 AND (MU-H)2(MU-3-S) (MU-CL)RU3(CO)8(SNCL3) [J].

ADAMS, RD ;

KATAHIRA, DA .

ORGANOMETALLICS, 1982, 1 (01) :53-59

[3] NONCLASSICAL POLYSULFIDE COMPLEXES - CAGE AND RING COMPOUNDS [(MECP)RU(PPH3)]2SX (X = 6, 4) [J].

AMARASEKERA, J ;

RAUCHFUSS, TB ;

RHEINGOLD, AL .

INORGANIC CHEMISTRY, 1987, 26 (13) :2017-2018

[4] SYNTHESIS OF CUBOIDAL (C5H4ME)4RU4E4 BY CONDENSATION OF (C5H4ME)RU(PPH3)2SH, (C5H4ME)RU(PPH3)2SEH [J].

AMARASEKERA, J ;

RAUCHFUSS, TB ;

WILSON, SR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) :14-16

[5] SYNTHESIS, STRUCTURE, AND PROPERTIES OF [CPRU(PR3)2]2(MU-S2)2+ - EFFECTS OF STRONG PI-DONATION IN A DISULFUR COMPLEX [J].

AMARASEKERA, J ;

RAUCHFUSS, TB ;

WILSON, SR .

INORGANIC CHEMISTRY, 1987, 26 (20) :3328-3332

[6] ROOM-TEMPERATURE ACTIVATION OF AN ALIPHATIC C-H BOND - SYNTHESIS AND STRUCTURE OF THE RUTHENIUM CLUSTERS [(MU-2-H)RU3(CO)8(MU-3-S)(ETA-2-CH2CME2NHCNHBUT)] AND [(MU-2-H)RU3(CO)9(MU-3-S-RU(CO)3(ETA-2-CH2CME2NHCNHBUT))] [J].

BODENSIECK, U ;

STOECKLIEVANS, H ;

SUSSFINK, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (03) :267-268

[7] REACTION OF H2FERU3(CO)13 WITH TERTIARY PHOSPHINES AND PHOSPHITES - INFLUENCE OF LIGAND SIZE AND BASICITY ON SUBSTITUTION SITE PREFERENCE - CRYSTAL AND MOLECULAR-STRUCTURE OF H2FERU3(CO)12(PME2PH) [J].

FOX, JR ;

GLADFELTER, WL ;

WOOD, TG ;

SMEGAL, JA ;

FOREMAN, TK ;

GEOFFROY, GL ;

TAVANAIEPOUR, I ;

DAY, VW ;

DAY, CS .

INORGANIC CHEMISTRY, 1981, 20 (10) :3214-3223

[8] SULFIDO AND RELATED DERIVATIVES OF (C5ME5)RUIII/IV [J].

HOUSER, EJ ;

DEV, S ;

OGILVY, AE ;

RAUCHFUSS, TB ;

WILSON, SR .

ORGANOMETALLICS, 1993, 12 (11) :4678-4681

[9] HYDRIDO-NITROSYL CLUSTERS [RU3(CO)10H(NO)], OR [OS3(CO)10H(NO)] AND THE MOLECULAR AND CRYSTAL-STRUCTURE OF [RU3(CO)7H(NO)(P(OME)3)3] [J].

JOHNSON, BFG ;

RAITHBY, PR ;

ZUCCARO, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (01) :99-104

[10] TRIMETHYLPHOSPHINE HYDRIDO-COMPLEXES AND HYDROXO-COMPLEXES OF RUTHENIUM - MULTI-NUCLEAR MAGNETIC-RESONANCE STUDIES ON MU-HYDRIDO-MU-HYDROXOHEXAKIS(TRIMETHYLPHOSPHINE)DIRUTHENIUM(I) - CRYSTAL-STRUCTURES OF DI-MU-HYDRIDO-DIHYDRIDOHEXAKIS(TRIMETHYLPHOSPHINE)DIRUTHENIUM(II) AND TRI-MU-HYDRIDO-HEXAKIS(TRIMETHYLPHOSPHINE)DIRUTHENIUM(II) TETRAFLUOROBORATE) [J].

JONES, RA ;

WILKINSON, G ;

COLQUOHOUN, IJ ;

MCFARLANE, W ;

GALAS, AMR ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (12) :2480-2487