LEWIS ADDUCTS OF FE(CO)42- AND CO(CO)4- IONS

被引:42
作者
RUFF, JK
机构
[1] Rohm and Haas Company, Redstone Research Laboratories Huntsville
关键词
D O I
10.1021/ic50066a006
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The metal carbonyl anions Fe(CO)42- and Co(CO)4- form adducts with indium tribromide or gallium tribromide of the type M(CO)4M′Br3n-. The complex ion Fe(CO)4InBr32- dissociates in solution to give a new ion Fe(CO)4InBr2-. This new ion will form adducts with amines and the preparation of the ions Fe(CO)4InBr2•(C2H5)3N- and Fe(CO)4InBr2•CsH5N- is also described. © 1968, American Chemical Society. All rights reserved.
引用
收藏
页码:1499 / &
相关论文
共 10 条