MECHANISM AND STEREOCHEMISTRY OF THE ENZYMIC CONVERSION OF PRENYL TO CHROMEN STRUCTURES, AS EFFECTED BY DEGUELIN CYCLASE

被引：6

作者：

BHANDARI, P ^{[1
]}

VANBRUGGEN, N ^{[1
]}

CROMBIE, L ^{[1
]}

WHITING, DA ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1989年 / 15期

关键词：

D O I：

10.1039/c39890000982

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

收藏

页码：982 / 984

页数：3

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[1] PROCHIRALITY TRANSFER IN THE ENZYMATIC CONVERSION OF (E)-[4'-C-13]-(6AS,12AS)-ROT-2'-ENONIC ACID INTO (6AS,12AS)-DEGUELIN - RESTRICTED STEREOSELECTIVITY IN AN ELECTRO-CYCLIZATION [J].

BEGLEY, MJ ;

CROMBIE, L ;

ROSSITER, J ;

SANDERS, M ;

WHITING, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (04) :353-356

[2] THE STEREOSPECIFIC GENERATION OF CHIRALLY LABELED BENZYLIC CENTERS IN ORTHO-PRENYLPHENOLS - 1'-R-[1'-H-3]-ROTENONIC AND 1'-S-[1'-H-3]-ROTENONIC ACID [J].

BHANDARI, P ;

CROMBIE, L ;

HARPER, MH ;

SANDERS, M ;

WHITING, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (15) :981-982

[3] BIOSYNTHETIC ORIGIN OF THE 2,2-DIMETHYLCHROMEN RING - FORMATION OF DEGUELIN BY A CYCLASE ENZYME FROM TEPHROSIA-VOGELLII [J].

CROMBIE, L ;

ROSSITER, J ;

WHITING, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (04) :352-353