[TBUSIO(REO4)]4, A MODEL-COMPOUND FOR METAL-OXIDES ON SILICATE SURFACES - SYNTHESIS FROM THE STABLE TRIOL TBUSI(OH)3 AND RE2O7

被引：87

作者：

WINKHOFER, N ^{[1
]}

ROESKY, HW ^{[1
]}

NOLTEMEYER, M ^{[1
]}

ROBINSON, WT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 05期

关键词：

D O I：

10.1002/anie.199205991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four ReO4 units each anchored to a silicon atom are found in the soluble metal-containing siloxane 1, accessible from the silanetriol tBuSi(OH)3 and Re2O7. The silanetriol does not undergo condensation reactions and can be prepared from tBuSiCl3 by hydrolysis in high yield. Compounds like 1 are interesting as model compounds for silicate supports bearing catalytically active transition-metal oxides.

引用

页码：599 / 601

页数：3

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