ANALYSIS OF DISPERSION OF CARBON-BLACK IN POLYMERIC MELTS AND ITS EFFECT ON COMPOUND PROPERTIES

被引:54
作者
RWEI, SP [1 ]
MANAS-ZLOCZOWER, I [1 ]
FEKE, DL [1 ]
机构
[1] CASE WESTERN RESERVE UNIV, DEPT CHEM ENGN, CLEVELAND, OH 44106 USA
关键词
D O I
10.1002/pen.760320209
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The dispersion of carbon black agglomerates within melts of polystyrene and high density polyethylene has been investigated. Analysis of the evolution of the fragment size distribution indicates that a coarse rupturing of the agglomerates occurs during the early stages of the dispersion. This is followed by a more gradual erosion of small aggregates from larger fragments. These observations compare quantitatively with results of dispersion studies performed in fluid media having a viscosity two orders of magnitude smaller than that of the polymeric melts. The influence of dispersion quality on certain physical properties of the resulting polymeric compounds, namely UV absorption characteristics and tensile strength properties. is also quantified.
引用
收藏
页码:130 / 135
页数:6
相关论文
共 6 条
[1]  
HIEMENZ PC, 1986, PRINCIPLES COLLOID S, P54
[2]   FLOC BREAKAGE IN AGITATED SUSPENSIONS - THEORY AND DATA-PROCESSING STRATEGY [J].
PANDYA, JD ;
SPIELMAN, LA .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1982, 90 (02) :517-531
[3]  
PANDYA JD, 1981, THESIS U DELAWARE NE
[4]   OBSERVATION OF CARBON-BLACK AGGLOMERATE DISPERSION IN SIMPLE SHEAR FLOWS [J].
RWEI, SP ;
MANAS-ZLOCZOWER, I ;
FEKE, DL .
POLYMER ENGINEERING AND SCIENCE, 1990, 30 (12) :701-706
[5]   CHARACTERIZATION OF AGGLOMERATE DISPERSION BY EROSION IN SIMPLE SHEAR FLOWS [J].
RWEI, SP ;
MANAS-ZLOCZOWER, I ;
FEKE, DL .
POLYMER ENGINEERING AND SCIENCE, 1991, 31 (08) :558-562
[6]  
S114 CAB CO TECHN RE