ONE-ELECTRON TRANSFER-REACTION OF PHENYL VINYL SULFIDES WITH DIOXYGEN - THE FATE OF THE INTERMEDIATE VINYL SULFIDE RADICAL CATIONS

被引：3

作者：

BENATI, L

MONTEVECCHI, PC

NANNI, D

SPAGNOLO, P

机构：

[1] DIPARTIMENTO CHIM ORGAN A MANGINI,VIALE RISORGIMENTO 4,I-40136 BOLOGNA,ITALY

[2] UNIV BASILICATA,DIPARTIMENTO CHIM,I-85100 POTENZA,ITALY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)73645-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mild reaction of pheyl vinyl sulfides with dioxygen can lead to the eventual formation of rearranged vinyl sulfides and/or carbonyl-containing sulfide products, which are believed to result from decomposition of initially-formed vinyl sulfide radical cations. Supporting evidence is provided by the comparable findings obtained from the one electron oxidation of one vinyl sulfide by cerium (IV) ammonium nitrate.

引用

页码：3595 / 3598

页数：4

共 15 条

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