THE SYNTHESIS AND CHARACTERIZATION OF MONODISPERSE POLY(ACRYLIC ACID) AND POLY(METHACRYLIC ACID)

被引：5

作者：

LEON, A

VINCENT, B

CAWDERY, N

机构：

[1] UNIV BRISTOL,SCH CHEM,CANTOCKS CLOSE,BRISTOL BS8 1TS,AVON,ENGLAND

[2] UNIV SANTIAGO,FAC CIENCIAS,DEPT QUIM,SANTIAGO,CHILE

来源：

COLLOID AND POLYMER SCIENCE | 1994年 / 272卷 / 04期

关键词：

POLY(ACRYLIC ACID); POLY(METHACRYLIC ACID); MONODISPERSE POLYELECTROLYTES; ANIONIC POLYMERIZATION;

D O I：

10.1007/BF00659455

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A number of polyacrylic (PAA) and polymethacrylic (PMAA) acids have been synthesized by living anionic polymerization of the monomeric tert-butyl esters followed by subsequent hydrolysis of the corresponding polyesters. The necessary precautions were taken in order to assure good molecular weight control, as well as high yields in the polymerization reactions. The intermediate and final polymers were characterized by gel permeation chromatography and NMR-H-1 spectrometry.

引用

页码：427 / 432

页数：6

共 10 条

[1] PREPARATION OF HIGH-PURITY, ANIONIC-POLYMERIZATION GRADE ALKYL METHACRYLATE MONOMERS [J].