FERROCENE-BRIDGED BIS(2,2'-BIPYRIDINES) - NEW TWEEZER-TYPE LIGANDS FOR TRANSITION-METAL IONS

被引：15

作者：

KONIG, B ^{[1
]}

NIMTZ, M ^{[1
]}

ZIEG, H ^{[1
]}

机构：

[1] GESELL BIOTECHNOL FORSCH MBH, D-38124 BRAUNSCHWEIG, GERMANY

来源：

TETRAHEDRON | 1995年 / 51卷 / 22期

关键词：

D O I：

10.1016/0040-4020(95)00281-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ferrocene-bridged bis(2,2'-bipyridines) 3 were synthesized from ferrocene-1,1'-dicarbaldehyde (1) and dimethyl-2,2'-bipyridines (2) via a two step condensation reaction. 3a and 3b can serve as tetradentate ligands for transition metal ions, whereby the silver(I) complex of 3a shows a restricted mobility on NMR time scale at room temperature.

引用

页码：6267 / 6272

页数：6

共 21 条

[1] AN IMPROVED SYNTHESIS OF FERROCENE-1,1'-DICARBALDEHYDE [J].

BALAVOINE, GGA ;

DOISNEAU, G ;

FILLEBEENKHAN, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) :381-382

[2]

BAUMGARTEN HE, 1973, ORG SYNTH, V5, P102

[3] SYNTHESIS AND COORDINATION CHEMISTRY OF NEW SCHIFF-BASE BIS(CROWN ETHER) LIGANDS CONTAINING RECOGNITION SITES FOR ALKALI-METAL AND TRANSITION-METAL GUEST CATIONS - CRYSTAL-STRUCTURE OF A COPPER(I)-POTASSIUM COMPLEX [J].

BEER, PD ;

CRANE, CG ;

DREW, MGB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (12) :3235-3242

[4] NOVEL MONO-FERROCENYL AND DI-FERROCENYL BIPYRIDYL LIGANDS - SYNTHESES, ELECTROCHEMISTRY, AND ELECTROPOLYMERIZATION STUDIES OF THEIR RUTHENIUM(II) COMPLEXES [J].

BEER, PD ;

KOCIAN, O ;

MORTIMER, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (11) :3283-3288

[5]

BOWLER BE, 1990, PROG INORG CHEM, V38, P259

[6] A BIMETALLIC HYDROFORMYLATION CATALYST - HIGH REGIOSELECTIVITY AND REACTIVITY THROUGH HOMOBIMETALLIC COOPERATIVITY [J].

BROUSSARD, ME ;

JUMA, B ;

TRAIN, SG ;

PENG, WJ ;

LANEMAN, SA ;

STANLEY, GG .

SCIENCE, 1993, 260 (5115) :1784-1788

[7] INTRAMOLECULAR LONG-DISTANCE ELECTRON-TRANSFER IN ORGANIC-MOLECULES [J].

CLOSS, GL ;

MILLER, JR .

SCIENCE, 1988, 240 (4851) :440-447

[8] SANDWICHES BRING A NEW ELEMENT TO MOLECULAR RECOGNITION [J].

CONSTABLE, EC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04) :407-408

[9]

DEBLAS AM, 1992, NATO ADV SCI I C-MAT, V371, P87

[10]

DURR H, 1991, FRONTIERS SUPRAMOLEC, P453

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