REAL-TIME ATTENUATED TOTAL REFLECTANCE FOURIER-TRANSFORM INFRARED-SPECTROSCOPY TO MONITOR MULTIACRYLATE POLYMERIZATION REACTIONS

被引：32

作者：

DIETZ, JE ^{[1
]}

ELLIOTT, BJ ^{[1
]}

PEPPAS, NA ^{[1
]}

机构：

[1] PURDUE UNIV, SCH CHEM ENGN, W LAFAYETTE, IN 47907 USA

来源：

MACROMOLECULES | 1995年 / 28卷 / 15期

关键词：

D O I：

10.1021/ma00119a001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Real-time attenuated total reflectance-Fourier transform infrared spectroscopy was used to follow the conversion during acrylate polymerizations by measuring the presence of functional groups at finite depths from the crystal surface. By varying the film thickness, the reactivity of multiacrylates could be spatially resolved. These results were compared to results from differential photocalorimetric studies.

引用

页码：5163 / 5166

页数：4

共 22 条

[1] PHOTOCHEMISTRY AND PHOTOPOLYMERIZATION ACTIVITY OF PERESTER DERIVATIVES OF BENZOPHENONE
ALLEN, NS
HARDY, SJ
JACOBINE, AF
GLASER, DM
YANG, B
WOLF, D
CATALINA, F
NAVARATNAM, S
PARSONS, BJ
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1991, 42 (05) : 1169 - 1178
[2] THE RADICAL POLYMERIZATION OF DIMETHACRYLATE MONOMERS - THE USE OF NMR SPECTROMETRY TO FOLLOW THE DEVELOPMENT OF NETWORK STRUCTURE
ALLEN, PEM
BENNETT, DJ
HAGIAS, S
HOUNSLOW, AM
ROSS, GS
SIMON, GP
WILLIAMS, DRG
WILLIAMS, EH
[J]. EUROPEAN POLYMER JOURNAL, 1989, 25 (7-8) : 785 - 789
[3] PHOTOSYNTHETIC MEMBRANES .3. INFLUENCE OF PHOTO-CROSS-LINKING ON PERMEATION AND DIFFUSION-COEFFICIENTS OF HYDROGEN AND CARBON-MONOXIDE THROUGH ASYMMETRIC MEMBRANES PREPARED BY PHOTOGRAFTING OF 1,6-HEXANEDIOL DIACRYLATE ONTO CELLULOSE
BELLOBONO, IR
SELLI, E
MARCANDALLI, B
COMI, D
RASTELLI, E
[J]. JOURNAL OF PHOTOCHEMISTRY, 1986, 35 (02): : 231 - 237
[4] DIMETHACRYLATE MONOMERS OF AROMATIC DIETHERS
BOWEN, RL
ANTONUCCI, JM
[J]. JOURNAL OF DENTAL RESEARCH, 1975, 54 (03) : 599 - 604
[5] CRYSTALLINE DIMETHACRYLATE MONOMERS
BOWEN, RL
[J]. JOURNAL OF DENTAL RESEARCH, 1970, 49 (04) : 810 - &
[6] THERMALLY AND LIGHT-INDUCED POLYMERIZATION OF ETHYL ACRYLATE AND METHYL-METHACRYLATE, STUDIES BY DSC
BRESSERS, HJL
KLOOSTERBOER, JG
[J]. POLYMER BULLETIN, 1980, 2 (03) : 201 - 204
[7] DAVIDSON RS, 1991, ROY SOC CH, V89, P400
[8] DAVIES AK, 1987, J RADIAT CURING, V14, P22
[9] DECKER C, 1990, J COATING TECHNOL, V62, P55
[10] DECKER C, 1988, MAKROMOL CHEM, V189, P2381

← 1 2 3 →