SPECTRA OF THE H-2 PHTHALOCYANINE IN LOW-TEMPERATURE MATRICES

被引:35
作者
BONDYBEY, VE
ENGLISH, JH
机构
[1] Contribution from Bell Laboratories, Murray Hill
关键词
D O I
10.1021/ja00507a004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Laser emission and excitation spectra of H2 phthalocyanine in solid Ar and Ne matrices were examined. The spectra display a sharp vibronic structure, both in excitation and emission. Polarization studies confirm the presence of two overlapping transitions in the red. It is suggested that a strong vibronic coupling is responsible for the appearance of several perpendicularly polarized bands below the Q3 origin. Copyright © 1979, American Chemical Society. All rights reserved.
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页码:3446 / 3450
页数:5
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