SYNTHETIC STUDIES ON PLANT-CELL WALL GLYCANS .7. STEREOSELECTIVE TOTAL SYNTHESIS OF DODECAGALACTURONIC ACID, A PHYTOALEXIN ELICITOR OF SOYBEAN

被引：30

作者：

NAKAHARA, Y ^{[1
]}

OGAWA, T ^{[1
]}

机构：

[1] RIKEN INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN

来源：

CARBOHYDRATE RESEARCH | 1990年 / 205卷

关键词：

D O I：

10.1016/0008-6215(90)80135-P

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

O-(α-d-Galactopyranosyluronic acid)-[(1 å 4)-O-(α-d-galactopyranosyluronic acid)]10-d-galactopyranuronic acid (1), an endogenous elicitor of the phytoalexin of soybean, was synthesized by way of highly stereoselective glycosylations that involved glycosyl fluorides as the donors and oxidation of the twelve primary hydroxyl groups in the α-(1 å 4)-linked galactododecaoside derivative. © 1990.

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页码：147 / 159

页数：13

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